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タイトル
和文:Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids. 
英文:Cationic rhodium(I)/bisphosphine complex-catalyzed cyclization of 1,6-diynes with carboxylic acids. 
著者
和文: Ken Tanaka, Shunsuke Saitoh, Hiromi Hara, 柴田祐.  
英文: Ken Tanaka, Shunsuke Saitoh, Hiromi Hara, Yu Shibata.  
言語 English 
掲載誌/書名
和文:Organic & Biomolecular Chemistry 
英文:Organic & Biomolecular Chemistry 
巻, 号, ページ Vol. 7    No. 23    pp. 4817-4820
出版年月 2009年 
出版者
和文:Royal Society of Chemistry 
英文:Royal Society of Chemistry 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1039/b913344e
アブストラクト A cationic rhodium(I)/bisphosphine complex catalyzes carboxylative cyclizations of 1,6-diynes, leading to cyclic dienyl carboxylates, in high yields with high chemo-, regio-, and stereoselectivities under mild reaction conditions. E.g., in presence of [Rh(cod)2]BF4/BIPHEP, reaction of MeC竕｡CCH2C(CO2Me)2CH2C竕｡CH gave 90% cyclopentane deriv. I (R = CO2Me). [on SciFinder(R)]

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