Synthesis of Pyridylphosphonates by Rhodium-Catalyzed [2+2+2] Cycloaddition of 1,6- and 1,7-Diynes with Diethyl Phosphorocyanidate.

Kenichi Kashima; Masahiro Ishii; Ken. Tanaka

doi:10.1002/ejoc.201403452

論文・著書情報

タイトル

和文:	Synthesis of Pyridylphosphonates by Rhodium-Catalyzed [2+2+2] Cycloaddition of 1,6- and 1,7-Diynes with Diethyl Phosphorocyanidate.
英文:	Synthesis of Pyridylphosphonates by Rhodium-Catalyzed [2+2+2] Cycloaddition of 1,6- and 1,7-Diynes with Diethyl Phosphorocyanidate.

著者

和文:	Kenichi Kashima, Masahiro Ishii, Ken. Tanaka.
英文:	Kenichi Kashima, Masahiro Ishii, Ken. Tanaka.

言語

English

掲載誌/書名

和文:	European Journal of Organic Chemistry
英文:	European Journal of Organic Chemistry

巻, 号, ページ

Vol. 2015 No. 5 pp. 1092-1099

出版年月

2015年

出版者

和文:	Wiley-VCH Verlag GmbH & Co. KGaA
英文:	Wiley-VCH Verlag GmbH & Co. KGaA

会議名称

和文:
英文:

開催地

和文:
英文:

DOI

https://doi.org/10.1002/ejoc.201403452

アブストラクト

The convenient and atom-economical synthesis of substituted bicyclic pyridylphosphonates was achieved by the cationic Rh(I)/H8-binap-complex-catalyzed [2+2+2] cycloaddn. of 1,6- and 1,7-diynes with di-Et phosphorocyanidate. These reactions may proceed via an azarhodacyclopentadiene intermediate in addn. to the rhodacyclopentadiene intermediate. [on SciFinder(R)]

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