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タイトル
和文:Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: isomerization of allyl propargyl ethers to allenic aldehydes and dienals. 
英文:Cationic rhodium(I) complex-catalyzed σ- and π-bond activation cascade: isomerization of allyl propargyl ethers to allenic aldehydes and dienals. 
著者
和文: 田中健, Eri Okazaki, Yu. Shibata.  
英文: Ken Tanaka, Eri Okazaki, Yu. Shibata.  
言語 English 
掲載誌/書名
和文:Pure and Applied Chemistry 
英文:Pure and Applied Chemistry 
巻, 号, ページ Vol. 82    No. 7    pp. 1453-1460
出版年月 2010年 
出版者
和文:International Union of Pure and Applied Chemistry 
英文:International Union of Pure and Applied Chemistry 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1351/PAC-CON-09-09-05
アブストラクト A cationic Rh(I)/1,1'-bis(diphenylphosphino)ferrocene (dppf) complex catalyzes isomerization of allyl propargyl ethers to allenic aldehydes in good yields at room temp. 40ﾂｰ. At 80ﾂｰ, carbonyl migration from allenic aldehydes proceeds further to give dienals in good yields. The cationic Rh(I)/dppf complex acts as a dual catalyst for activation of ﾏ? and ﾏ?bonds in these isomerization reactions. [on SciFinder(R)]

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