Positively Charged Base Surrogate for Highly Stable “Base Pairing” through Electrostatic and Stacking Interactions

Hiromu Kashida; Hidehiro Ito; Taiga Fujii; Takamitsu Hayashi; Hiroyuki Asanuma

doi:10.1021/ja9013002

論文・著書情報

タイトル

和文:
英文:	Positively Charged Base Surrogate for Highly Stable “Base Pairing” through Electrostatic and Stacking Interactions

著者

和文:	Hiromu Kashida, 伊藤栄紘, Taiga Fujii, Takamitsu Hayashi, Hiroyuki Asanuma.
英文:	Hiromu Kashida, Hidehiro Ito, Taiga Fujii, Takamitsu Hayashi, Hiroyuki Asanuma.

言語

English

掲載誌/書名

和文:
英文:	Journal of the American Chemical Society

巻, 号, ページ

Vol. 131 No. 29 pp. 9928-9930

出版年月

2009年

出版者

和文:
英文:	American Chemical Society

会議名称

和文:
英文:

開催地

和文:
英文:

公式リンク

http://dx.doi.org/10.1021/ja9013002

DOI

https://doi.org/10.1021/ja9013002

アブストラクト

“Base Pairing” of cationic dyes (p-methylstilbazole) were incorporated into oligodeoxyribonucleotides (ODNs). This “Base Pairing” greatly stabilized the duplex through electrostatic and stacking interactions. The melting temperature of modified ODN was higher than those of neutral dyes and native base pairs. Further stabilization of the duplex was observed when the number of cationic dyes increased.

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