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タイトル
和文:Spin Crossover by Encapsulation 
英文:Spin Crossover by Encapsulation 
著者
和文: 小野 公輔, 吉沢 道人, 穐田 宗隆, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita.  
英文: Kosuke Ono, Michito Yoshizawa, Munetaka Akita, Tatsuhisa Kato, Yoshihide Tsunobuchi, Shin-ichi Ohkoshi, Makoto Fujita.  
言語 English 
掲載誌/書名
和文:Journal of the American Chemical Society 
英文:Journal of American Chemical Society 
巻, 号, ページ vol. 131    no. 8    pp. 2782–2783
出版年月 2009年1月 
出版者
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英文: 
会議名称
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英文: 
開催地
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英文: 
公式リンク http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=ORCID&SrcApp=OrcidOrg&DestLinkType=FullRecord&DestApp=WOS_CPL&KeyUT=WOS:000264792300014&KeyUID=WOS:000264792300014
 
DOI https://doi.org/10.1021/ja8089894
アブストラクト Encapsulation by synthetic hosts can transform the spin states of square planar Ni(II)(acen) and Co(II)(tap) complexes. Upon encapsulation, the red Ni(II) diamagnetic state was converted into a green paramagnetic state, whereas the Co(II) low spin (S = 1/2) state was changed into a coupled (S = 1/2 and S = 3/2) state. The host cages are noninnocent and host−guest interactions within the confined cavity influence the resultant properties of the enclathrated metal complexes.

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