Home >

news ヘルプ

論文・著書情報


タイトル
和文:Aerobic Oxidative Olefination of Benzamides with Styrenes Catalyzed by a Moderately Electron-Deficient CpRh(III) Complex with a Pendant Amide. 
英文:Aerobic Oxidative Olefination of Benzamides with Styrenes Catalyzed by a Moderately Electron-Deficient CpRh(III) Complex with a Pendant Amide. 
著者
和文: Ryo Yoshimura, Yu Shibata, Takayuki Yamada, Ken. Tanaka.  
英文: Ryo Yoshimura, Yu Shibata, Takayuki Yamada, Ken. Tanaka.  
言語 English 
掲載誌/書名
和文:Journal of Organic Chemistry 
英文:Journal of Organic Chemistry 
巻, 号, ページ         pp. Ahead of Print
出版年月 2019年1月21日 
出版者
和文:American Chemical Society 
英文:American Chemical Society 
会議名称
和文: 
英文: 
開催地
和文: 
英文: 
DOI https://doi.org/10.1021/acs.joc.8b02875
アブストラクト It has been established that a newly developed moderately electron-deficient cyclopentadienyl (Cp)-Rh(III) complex, bearing ester and pendant amide moieties on the Cp ring [CpARh(III)], is able to catalyze the aerobic oxidative olefination of benzamides, bearing nonspecial carbamoyl groups, with styrenes including disubstituted ones at relatively low temp. (60-80 ツーC). The presence of both the ester and pendant acidic N-phenylcarbamoyl moieties on the CpA ligand play important roles in facilitation of the catalysis without sacrificing thermal stability of the complex. [on SciFinder(R)]

©2007 Institute of Science Tokyo All rights reserved.