Synthesis and characterization of a uranyl(vi) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative
英文:
Synthesis and characterization of a uranyl(vi) complex with 2,6-pyridine-bis(methylaminophenolato) and its ligand-centred aerobic oxidation mechanism to a diimino derivative
<jats:p>Both aminomethylene groups of a uranyl(<jats:sc>vi</jats:sc>) complex bearing a 2,6-pyridine-bis(methylaminophenolato) ligand are oxidized to azomethine ones by an O<jats:sub>2</jats:sub> molecule under an ambient atmosphere to provide a diimino derivative of the parent uranyl(<jats:sc>vi</jats:sc>) complex.</jats:p>
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