論文

• Hideki Abe, Hiroshi Mizoguchi, Ryuto Eguchi, Hideo Hosono. Exploration of heterogeneous catalyst for molecular hydrogen ortho-para conversion, EXPLORATION, 4, June 2024.
• Hiroshi Mizoguchi, Yuta Osawa, Masato Sasase, Naoki Ohashi, Masaaki Kitano, Hideo Hosono. Ammonia Cracking Catalyzed by Ni Nanoparticles Confined in the Framework of CeO2 Support, J. Phys. Chem. Lett., Vol. 14, pp. 9516-9520, Oct. 2023.
• Xinyi He, Seiya Nomoto, Takehito Komatsu, Takayoshi Katase, Terumasa Tadano, Suguru Kitani, Hideto Yoshida, Takafumi Yamamoto, Hiroshi Mizoguchi, Keisuke Ide, Hidenori Hiramatsu, Hitoshi Kawaji, Hideo Hosono, Toshio Kamiya. Hydride anion substitution boosts thermoelectric performance of polycrystalline SrTiO3 via simultaneous realization of reduced thermal conductivity and high electronic conductivity, Adv.Funct. Mater., Vol. 33, 28, p. 2313144, Apr. 2023.
• Xinyi He, Seiya Nomoto, Takehito Komatsu, Takayoshi Katase, Terumasa Tadano, Suguru Kitani, Hideto Yoshida, Takafumi Yamamoto, Hiroshi Mizoguchi, Keisuke Ide, Hidenori Hiramatsu, Hitoshi Kawaji, Hideo Hosono, Toshio Kamiya. Hydride anion substitution boosts thermoelectric performance of polycrystalline SrTiO3 via simultaneous realization of reduced thermal conductivity and high electronic conductivity, Adv.Funct. Mater., Vol. 33, 28, p. 2313144, Apr. 2023.
• Xinyi He, Seiya Nomoto, Takehito Komatsu, Takayoshi Katase, Terumasa Tadano, Suguru Kitani, Hideto Yoshida, Takafumi Yamamoto, Hiroshi Mizoguchi, Keisuke Ide, Hidenori Hiramatsu, Hitoshi Kawaji, Hideo Hosono, Toshio Kamiya. Hydride anion substitution boosts thermoelectric performance of polycrystalline SrTiO3 via simultaneous realization of reduced thermal conductivity and high electronic conductivity, Adv.Funct. Mater., Vol. 33, 28, p. 2313144, Apr. 2023.
• Hiroshi Mizoguchi, Sang-Won Park, Takayoshi Katase, Jiaohao Yu, Junjie Wang, Hideo Hosono. Unique Conduction Band Minimum of Semiconductors Possessing a Zincblende-Type Framework, Inorg. Chem., Vol. 61, pp. 10359, June 2022.
• Mohammad Khazaei, Ahmad Ranjbar, Yoon-Gu Kang, Yunye Liang, Rasoul Khaledialidusti, Soungmin Bae, Hannes Raebiger, Vei Wang, Myung Joon Han, Hiroshi Mizoguchi, Mohammad S. Bahramy, Thomas D. Kuhne, Rodion V. Belosludov, Kaoru Ohno, Hideo Hosono. Electronic Structures of Group III–V Element Haeckelite Compounds: A Novel Family of Semiconductors, Dirac Semimetals, and Topological Insulators, Adv. funct. mater., 32, 2110930(1-10), Feb. 2022.
• Hiroshi Mizoguchi, Sang-Won Park, Hideo Hosono. A View on Formation Gap in Transition Metal Hydrides and Its Collapse, J. Am. Chem. Soc, 143, 8821–8828, July 2021.
• Hiroshi Mizoguchi, Sang-Won Park, Takayoshi Katase, Grigori V. Vajenine, Joonho Bang, Junghwan Kim, Hideo Hosono. Origin of metallic nature of Na₃N, J. Am. Chem. Soc., vol. 143, p. 69-72, Dec. 2020.
• Hiroshi Mizoguchi, Joonho Bang, Takeshi Inoshita, Toshio Kamiya, Hideo Hosono. On the origin of the negative thermal expansion behavior of YCu, INORG. CHEM., American Chemical Society, Vol. 58, pp. 11819-11827, Aug. 2019.
• Hiroshi Mizoguchi, Satoru Matsuishi, Sang-Won Park, Hideo Hosono. Hydrogen-Insertion-Induced Itinerant Ferromagnetism in Zr2CoH4.8 with Co Chains, Journal of Physical Chemistry C, Vol. 123, pp. 14964-14968, June 2019.  公式リンク  
  
• Hiroshi Mizoguchi, Sang-Won Park, Kazuhisa Kishida, Masaaki Kitano, Junghwan Kim, Masato Sasase, Takashi Honda, Kazutaka Ikeda, Toshiya Otomo, Hideo Hosono. Zeolitic Intermetallics: LnNiSi (Ln = La–Nd), Journal of the American Chemical, American Chemical Society, Vol. 141, No. 8, pp. 3376–3379, Feb. 2019.  公式リンク  
  
• Takaya Ogawa, Yasukazu Kobayashi, Hiroshi Mizoguchi, Masaaki Kitano, Hitoshi Abe, Tomofumi Tada, Yoshitake Toda, Yasuhiro Niwa, Hideo Hosono. High Electron Density on Ru in Intermetallic YRu₂: The Application to Catalyst for Ammonia Synthesis, J. Phys. Chem. C, Vol. 122, pp. 10468–10475, Apr. 2018.
• Sang-Won Park, Hiroshi Mizoguchi, Haruhiro Hiraka, Kazutaka Ikeda, Toshiya Otomo, Hideo Hosono. Transformation of the Chromium Coordination Environment in LaCrAsO Induced by Hydride Doping: Formation of La2Cr2As2OyHx, INORG. CHEM. COMMUN., American Chemical Society, Vol. 56, No. 22, pp. 13642–13645, Oct. 2017.  公式リンク  
  
• Hiroshi Mizoguchi, SangWon Park, Takashi Honda, Kazutaka Ikeda, Toshiya Otomo, HIDEO HOSONO. Cubic Fluorite-Type CaH2 with a Small Bandgap, J. AM. CHEM. SOC., American Chemical Society, Vol. 139, pp. 11317-11320, Aug. 2017.  公式リンク  
  
• Hiroshi Mizoguchi, Yoshinori Muraba, Daniel Clifford Fredrickson, Satoru Matsuishi, TOSHIO KAMIYA, HIDEO HOSONO. The Unique Electronic Structure of Mg2Si: Shaping the Conduction Bands of Semiconductors with Multi-center Bonding, Angewandte Chemie International Edition, Wiley-VCH, Vol. 56, pp. 10135-10139, May 2017.  公式リンク  
  
• Hiroshi Mizoguchi, Masaaki Okunaka, Masaaki Kitano, Satoru Matsuishi, Toshiharu Yokoyama, Hideo Hosono. Hydride-Based Electride Material, LnH2 (Ln = La, Ce, or Y), Inorganic Chemistry, American Chemical Society, Vol. 55, No. 17, p. 8833, Aug. 2016.
• Hiroshi Mizoguchi, SangWon Park, Haruhiro Hiraka, Kazutaka Ikeda, Toshiya Otomo, HIDEO HOSONO. An Anti CuO₂-type Metal Hydride Square Net Structure in Ln₂M₂As₂H_x (Ln = La or Sm, M = Ti, V, Cr, or Mn), Angew. Chem. Int. Ed., Wiley-VCH, Vol. 54, pp. 2932-2935, 2015.
• H. Mizoguchi, S. Park, H. Hiraka, K. Ikeda, T. Otomo, H. Hosono. New LaMAsHx (M = Co, Ni, or Cu) Arsenides with Covalent M–H Chains, J AM CHEM SOC, Vol. 136, p. 17390, Dec. 2014.
• 溝口拓, N. S. P. Bhuvanesh, Young-Il Kim, 大原智, P. M. Woodward. Hydrothermal Crystal Growth and Structure Determination of Double Hydroxides LiSb(OH)₆, BaSn(OH)₆, and SrSn(OH)₆, Inorganic Chemistry, The American Chemical Society, Vol. 53, No. 19, p. 10570, Sept. 2014.  公式リンク  
  
• 朴 相源, 溝口 拓, 樹神 克明, 社本 真一, 大友季哉, 松石 聡, 神谷 利夫, 細野 秀雄. Magnetic Structure and Electromagnetic Properties of LnCrAsO witha ZrCuSiAs-type Structure (Ln = La, Ce, Pr, and Nd), INORG. CHEM., American Chemical Society, Vol. 52, p. 13363, Nov. 2013.
• Mizoguchi, H., Chen, P., Boolchand, P., Ksenofontov, V., Felser, C., Barnes, P. W., Woodward, P. M.. Electrical and optical properties of Sb-doped BaSnO₃, Chem. Mater., Vol. 25, pp. 3858-3866, Aug. 2013.
• K. Nakayama, E. Ieki, Y. Tanaka, T. Sato, T. Takahashi, T. Kuroda, H. Mizoguchi, S.W. Kim, H. Hosono. Angle-resolved photoemission spectroscopy of Co-based boride superconductor LaCo_1.73Fe_0.27B₂, Physical Review B, Vol. 86, p. 014503, July 2012.
• R. D. Shannon, O. Medenbach, Hiroshi Mizoguchi, M. A. Subramanian, R. X. Fischer. Optical constants and crystal chemical parameters of Sc₂W₃O₁₂, Mater. Res. Bull., Vol. 47, No. 1, pp. 235-238, Jan. 2012.
• Naoki Imamura, Hiroshi Mizoguchi, Hideo Hosono. Superconductivity in LaT_MBN and La₃T_M2B₂N₃ (T_M = Transition Metal) Synthesized under High Pressure, J. Am. Chem. Soc, Vol. 134,, pp. 2516-2519, 2012.
• Hiroshi Mizoguchi, Toshio Kamiya, Hideo Hosono. Superconducting compounds with metallic square net, Solid State Commun, Vol. 152, pp. 666-670, 2012.
• Gihun Ryu, Sung Wng Kim, Hiroshi Mizoguchi, Satoru Matsuishi, Hideo Hosono. Superconductivity in a PbFCl-type pnictide:NbSiAs, Europhysics Lett., Vol. 99, No. 27002, pp. 1-6, 2012.
• Yanpeng Qi, Satoru Matsuishi, Jiangang Guo, Hiroshi Mizoguchi, Hideo Hosono. Superconductivity in Defective Pyrite-Type Iridium Chalcogenides Ir_xCh₂ (Ch = Se and Te), Phys. Rev. Lett, Vol. 109, pp. 217002-1 - 217002-5, 2012.
• H.Mizoguchi, Y.Michiue, A. W. Sleight, M. A. Subramanian*. Undulating Layers in a New Rhodate Network: Structure of Bi_1.4CuRh₅O₁₁, Inorg. Chem., Vol. 50, page 10397, Sept. 2011.
• H. Mizoguchi, L. N. Zakharov, N. S. P. Bhuvanesh, A. W. Sleight, M. A. Subramanian. Synthesis and crystal structure of two new cerium rhodium oxides: Ce_2/3-xRh₂O₄ (x~0.12) with Ce mixed valency and CeRh₂O₅, J. Solid State Chem., Vol. 184, p. 1381-1386, Apr. 2011.
• Hiroshi Mizoguchi, Satoru Matsuishi, Masahiro Hirano, Makoto Tachibana, Eiji Takayama-Muromachi, Hitoshi Kawaji, Hideo Hosono. Coexistence of Light and Heavy Carriers Associated with Superconductivity and Antiferromagnetism in CeNi_0.8Bi₂ with a Bi Square Net, Phys. Rev. Lett, Vol. 106, pp. 057002-1～057002-4, 2011.
• Hiroshi Mizoguchi, Toshio Kamiya, Satoru Matsuishi, Hideo Hosono. A germanate transparent conductive oxide, Nature Comm, Vol. 2, No. 470, pp. 1 - 5, 2011.
• Hiroshi Mizoguchi, Toshiaki Kuroda, Toshio Kamiya, Hideo Hosono. LaCo₂B₂: A Co-Based Layered Superconductor with a ThCr₂Si₂-Type Structure, Phys. Rev. Lett., Vol. 106, pp. 237001-1 ～ 237001-4, 2011.
• K. Kodama, S. Wakimoto, N. Igawa, S. Shamoto, H. Mizoguchi, H. Hosono. Crystal and magnetic structures of the superconductor CeNi_0.8Bi₂, Phys. Rev. B, Vol. 83, pp. 214512, 2011.
• Hiroshi Mizoguchi, Hideo Hosono. A Metal-Insulator Transition in R₂O₂Bi with an Unusual Bi^2- Square Net (R = Rare Earth or Y), J. Am. Chem. Soc, Vol. 133, pp. 2394-2397, 2011.
• H. Mizoguchi, H. Hosono. La₂Sb, a layered superconductor with metal-metal bonds, CHEMICAL COMMUNICATIONS, Vol. 47, pp. 3778-3780, 2011.
• Hiroshi Mizoguchi, A. W. Sleight, M. A. Subramanian. New Oxides Showing an Intense Blue Color Based on Mn Coordination, Inorg. Chem., Vol. 50, No. 1, pp. 10-12, Dec. 2010.
• A. J. Gatimu, H. Mizoguchi, A. W. Sleight, M. A. Subramanian. Verway-type transition within the Pb₃Rh_7-xMn_xO₁₅ solid solution, J. Solid State Chem., vol. 183, pp. 866-870, 2010.
• Andrew E. Smith, Hiroshi Mizoguchi, Kris Delaney, Nicola A. Spaldin, Arthur W. Sleight, M. A. Subramanian. Mn³⁺ in Trigonal Bipyramidal Coordination: A New Blue Chromophore, J. Am. Chem. Soc., Vol. 131, pp. 17084-17086, Nov. 2009.
• Hiroshi Mizoguchi, A. P. Ramirez, T. Siegrist, L. N. Zakharov, A. W. Sleight, M. A. Subramanian. Possible Verwey-Type Transition in Pb₃Rh₇O₁₅, Chem. Mater., Vol. 21, pp. 2300-2305, Apr. 2009.
• Hiroshi Mizoguchi, L. N. Zakharov, W. J. Marshall, A. W. Sleight, M.A.Subramanian. AA'Rh₆O₁₂: A New Family of Rhodium Oxides Exhibiting High Thermopower Coupled with High Electrical Conductivity, Chem. Mater., Vol. 21, pp. 994-999, Feb. 2009.
• H. Mizoguchi, L. N. Zakharov, A. P. Ramirez, W. J. Marshall, A. W. Sleight, M. A. Subramanian. New A_2/3-xRh₂O₄ Compounds with the CaFe₂O₄ Structure Where A is a Rare Earth or Bi, Inorg. Chem., Vol. 48, pp. 204-208, Dec. 2008.
• H. Mizoguchi, A. W. Sleight, M. A. Subramanian. Low temperature synthesis and characterization of SnTa₂O₆, Mater. Res. Bull., Vol. 44, pp. 1022-1024, Nov. 2008.
• H. Mizoguchi, A. Wattiaux, R. Kykyneshi, J. Tate, A. W. Sleight, M. A. Subramanian. Synthesis and characterization of Sn²⁺ oxides with the pyrochlore structure, Mater. Res. Bull., Vol. 43, pp. 1943-1948, Mar. 2008.
• H. Mizoguchi, A. P. Ramirez, L.N. Zakharov, A. W. Sleight, M. A. Subramanian. Bi_2/3Ce_1/3Rh₂O₅ : a new mixed-valent Rh oxide with hitherto unknown structure, J. Solid State Chem., Vol. 181, pp. 56-60, Dec. 2007.
• H. Mizoguchi, W. J. Marshall, A. P. Ramirez, A. W. Sleight, M. A. Subramanian. Evidence for charge ordering in the mixed-valent compound (Bi₆O₅)Rh³⁺₈Rh⁴⁺₄O₂₄, J. Solid State Chem., Vol. 180, pp. 3463-3468, Oct. 2007.
• H. Mizoguchi, D. L. Gray, F. Q. Huang, J. A. Ibers. Structures and Bonding in K_0.91U_1.79S₆ and KU₂Se₆, Inorg. Chem., Vol. 45, pp. 3307-3311, Mar. 2006.
• Hiroshi Mizoguchi, Patrick M. Woodward. Electronic Structure Studies of Main Group OxidesPossessing Edge-Sharing Octahedra: Implications forthe Design of Transparent Conducting Oxides, Chem. Mater., Vol. 16, pp. 5233-5248, Nov. 2004.
• Hiroshi Mizoguchi, Patrick M. Woodward, Cheol-Hee Park, D. A. Keszler. Strong Near-Infrared Luminescence in BaSnO₃, J. Am. Chem. Soc., Vol. 126, pp. 9796-9800, July 2004.
• Hiroshi Mizoguchi, Hank W. Eng, Patrick M. Woodward. Probing the Electronic Structures of Ternary Perovskite and Pyrochlore Oxides Containing Sn or Sb, Inorg. Chem. 2004, 43, 1667ー1680, Vol. 43, pp. 1667-1680, Feb. 2004.
• Hiroshi Mizoguchi, Patrick M. Woodward, Song-Ho Byeon, J. B. Parise. Polymorphism in NaSbO₃: Structure and Bonding in Metal Oxides, J. Am. Chem. Soc., Vol. 126, pp. 3175-3184, Feb. 2004.
• H. Mizoguchi, N. S. P. Bhuvanesch, P. M. Woodward. Optical and electrical properties of the wide gap, n-type semiconductors ZnBi₂O₆ and MgBi₂O₆, Chem. Commun., Vol. 2003, pp. 1084-1085, Apr. 2003.

著書

• P. M. Woodward, H. Mizoguchi, Y.-I. Kim, M. Strufuzs. The electronic structure of metal oxides, Metal Oxides: Chemistry and Applications, Chemical Industries (Boca Raton, FL, United States), Vol. 108, pp. 133-193, Jan. 2006.

国際会議発表 (査読有り)

• Hiroshi Mizoguchi, Takayoshi Katase, Sang-Won Park, Hideo Hosono. Electroactive role of crystallographic cavity in Na3N, Materials Research Meeting 2021, Dec. 2021.
• Hiroshi Mizoguchi. The unique compounds having crystallographic cavity space as an electronically active site, STAC-10, Aug. 2017.
• Hiroshi Mizoguchi. Chemical bonding view of transparent conducting oxides, 21st International Conference Solid State Ionics, June 2017.

国際会議発表 (査読なし・不明)

• 溝口拓. Search For New Materials Including TCOｓ and Superconductors, ISS2012, 2012.
• Hiroshi Mizoguchi, Toshiaki Kuroda, Toshio Kamiya, Hideo Hosono. Superconducting compounds with square net, International Conference on Novel SuperConductivity in Taiwan, Aug. 2011.
• H. Mizoguchi, M. Hirano, H. Hosono, S. Matsuishi, T. Kuroda, T. Kamiya, H. Kawaji, M. Tachibana, E. Takayama-muromachi. Superconducting compounds with square net, International Workshop on Novel Superconductors and Super Materials 2011 (NS2 2011), Mar. 2011.
• H. Mizoguchi, H. Hosono. Novel type of TCO: SrGeO₃ with perovskite structure, 2010 MRS Fall Meeting, Dec. 2010.

国内会議発表 (査読なし・不明)

• 小林靖和, 小川敬也, 和田裕之, 溝口拓, 北野政明, 細野秀雄. 気相レーザーアブレーション法を用いたアンモニア合成に向けたYRu2金属間化合物ナノ微粒子の合成, 化学工学会第50回大会, Sept. 2018.
• 溝口拓, 朴相源, 細野秀雄, 本田 孝志, 池田一貴, 大友季哉. 蛍石型CaH2合成の試み, 日本セラミックス協会2018年 年会, Mar. 2018.
• 溝口拓, 村場善行, フレッドリクソンダニエル, 松石聡, 神谷利夫, 細野秀雄. 多中心結合からなる伝導帯を持つ半導体Mg2Si, 日本セラミックス協会第30回秋季シンポジウム, Sept. 2017.
• 溝口拓, 奥中正昭, 北野政明, 松石聡, 横山壽治, 細野秀雄. 水素化物エレクトライド、LnH2の合成及びそのアンモニア合成への適用, 日本セラミックス協会秋季シンポジウム, 2016.
• 溝口拓. 透明伝導性酸化物における化学結合, 日本セラミックス協会秋季シンポジウム, 2015.
• 溝口拓, 朴相源, 細野秀雄, 平賀晴弘, 池田一貴, 大友季哉. LaMAs (M=3d遷移金属) の水素化, 日本ｾﾗﾐｯｸｽ協会第27回秋季シンポジウム, Sept. 2014.
• 溝口拓, P. M. Woodward, 細野秀雄. p-block元素の酸化物の電子構造とその透明伝導体材料への適用, 日本ｾﾗﾐｯｸｽ協会第26回秋季シンポジウム, Sept. 2013.

その他の論文・著書など

• 溝口拓. コバルト化合物の超伝導, パリティ, 丸善, Vol. 27, No. 5, pp. 28-30, Apr. 2012.

特許など

• 細野秀雄, 原亨和, 北野政明, 溝口拓, 横山壽治, 山縣亨介. 金属担持物、担持金属触媒及び該触媒を用いるアンモニア合成法. 特許. 登録. 国立大学法人東京工業大学, 国立研究開発法人科学技術振興機構. 2016/11/09. 特願2017-550340. 2018/10/04. 再表2017/082265. 特許第6802544号. 2020/12/01 2020. Dec.
• 細野秀雄, 横山壽治, 北野政明, 溝口拓, 小川敬也. ラーベス相金属間化合物、金属間化合物を用いた触媒、及びアンモニア製造方法. 特許. 登録. 国立大学法人東京工業大学, 国立研究開発法人科学技術振興機構. 2016/09/15. 特願2017-539977. 2018/08/09. 再表2017/047709. 特許第6737455号. 2020/07/20 2020.
• 細野秀雄, 斉　彦鵬, 郭　建剛, 今村直貴, 松石聡, 溝口拓, 藤津悟. 超伝導化合物とその製造方法. 特許. 登録. 国立大学法人東京工業大学. 2012/10/05. 特願2012-223283. 2014/04/24. 特開2014-073948. 特許第5664981号. 2014/12/19 2014.

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